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Research Detail

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Md. Shafiqul Islam
Department of Geology and Mining, University of Rajshahi, Rajshahi 6205, Bangladesh

Md. Abdullah Al Mamun
Department of Chemistry, University of Rajshahi, Rajshahi 6205, Bangladesh.

Md. Nazmul Islam
Department of Chemistry, University of Rajshahi, Rajshahi 6205, Bangladesh

The present study evaluated the leaching of arsenic from sludge/waste of seven SONO filters that were operated in Rajarampur of Chapai Nawabganj district. For this, Toxicity Characteristic Leaching Procedure (TCLP) test was performed. To understand actual leaching of arsenic, a Simulated Natural Column (SNC) that is comparable to natural mature landfill was devised. Total arsenic concentration (AsT) was measured by HG-AAS. The studied arsenic waste/sludge, having 7.0-9.2% solid content, were alkaline in nature (pH values of 7.9-8.7) and had arsenic and iron concentrations of 4.54-5.50 and 480-1039 mg kg- 1 respectively. The TCLP test reveals that 6.4-19.4% (average 14%) of arsenic was leached from the waste (average leachate AsT before and after TCLP were 5.04 and 0.71 mg kg-1 respectively). After 102 days of continuous operation in SNC, AsT in the leachate was found to be 0.223 mg L-1, although initial AsT was 0.350 mg L-1. It was observed that AsT in SNC leachate increased up to 54 days (corresponding to 1.741 mg L-1) and then decreased in reciprocal quadratic pattern. Comparison shows that TCLP underpredicts 14.2% of arsenic leaching than that of SNC. Since leachate AsT in both methods did not exceed the USEPA regulated level of 5 mg L-1, the studied waste/sludge was not hazardous.

  Arsenic, leaching, TCLP, arsenic removal unit, arsenic waste/sludge, modified column.
  Rajarampur locality of Nawabganj Sadar thana of Chapai Nawabganj District
  
  
  Risk Management in Agriculture
  Arsenic

To evaluate actually whether a spent filter (arsenic sludge/waste) when dumped in traditional manner would create serious environmental problems in Bangladesh or not, both in short and in long term considerations.

Site selection: The study area is situated at the northwestern part of Bangladesh, namely, Rajarampur locality of Nawabganj Sadar thana of Chapai Nawabganj District. Materials: The chemicals used in this investigation were of high purity analytical grade. Distilled deionized water (DDW), obtained through the deionization plant (TYP-2500, Deng Yuan, China), was used throughout. Perkin Elmer pure atomic spectroscopy standard solution (Perkin Elmer, USA) of arsenic (CAS # 7440-38-2) was used for calibration of arsenic. A number of standard solutions, reducing solutions, buffer solutions, ternary acid mixture and other solutions were prepared according to respective standard procedures (APHA 1995; Hesse 1994; Shimadzu). The other reagents were from Merck (Germany), Fluka (Switzerland) and Sigma Aldrich (USA). TCLP tests: First preliminary TCLP evaluations were performed with a minimum 100g of semi-solid waste for: (1) Determination of percent solids, (2) Determination of whether the solid portion of the waste requires particle size reduction or not and (3) Determination of which of the extraction fluids are to be used for the TCLP test. Leaching tests under Simulated Natural Column (SNC): The natural disposal conditions considered in the study include on land disposal in typical non-hazardous landfill dump or backyard and dumping in household ditch. Microbially active, mildly alkaline, anaerobic conditions characterize mature landfill (Christensen et al 2001). In the experimental section a PVC column, 30 inch in length and 6.3 inch in diameter, was operated in down flow mode. A syringe delivered 0.35 mL/min of influent, maintaining the water level at a total saturated bed volume of about 13 L. The column was operated at room temperature of 30ºC. 5 cm thick pea gravel layers (0.4-1.0 cm diameter) were provided above and below of the active bed ensuring even flow distribution. Characterization of sludge, materials of SNC and feed water: The arsenic waste/sludge of SONO filters were characterized by measuring solid content, pH, redox potential, concentrations of arsenic and iron. The materials of SNC and feed water were characterized by measuring pH, redox potential, electrical conductivity, dissolved oxygen, total dissolved solids, concentrations of arsenic, iron, calcium and magnesium, total coliform and fecal coliform. All the parameters were measured using standard procedures and properly calibrated instruments. Extraction and analysis for metal concentrations: Prior to analysis of water samples for total arsenic (AsT) and total iron (FeT) the aqueous samples were subjected to mild digestion with HNO3 (APHA 1995). But the water samples were not pretreated for estimation of calcium and magnesium. For estimation of AsT, FeT, Ca and Mg in soil samples, these were digested with H2SO4-HClO4 acid mixtures (Sakamoto et al 2001; Hesse 1994; Shimadzu).Microbiological examination: Membrane filter (MF) method was used to count total and fecal coliform bacteria. A volume of 100 ml water was filtered through gridded nontoxic Nitrocellulose membrane filter (Millipore, USA), 47 mm in diameter having pore size of 0.45 µm, under manual vacuum condition. Statistical analyses: The datasets were treated separately for analyzing basic statistical parameters and making cross tabulations and cross plots. The statistical software used in the data analyses includes SPSS (release 13.0) statistical software package (SPSS Inc., Chicago, Illinois, 2004), STATGRAPHICS Centurion XV (release 12.2.14) software (StatPoint Technologies, Inc., Warrenton, Virginia, 2007). Mathematical models were established based upon simple and multiple regression analysis using SPSS, STATGRAPHICS Centurion XV and CurveExpert (release 1.34) and Microsoft Excel (release 12.0.4518.1014, 2006). The models were cross-checked by analyzing ANOVA, P value, r value (Pearson correlation coefficient) and Durbin–Watson statistics.

  J. Life Earth Sci., Vol. 6: 19-26, 2011 ISSN 1990-4827
  
Funding Source:
  

It is obvious that most of the arsenic is leached within first 10 years. After 50 years, there will virtually no change in cumulative arsenic concentration in the leachates.

  Journal
  


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