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Research Detail

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A. Islam
Department of Soil Science, Dhaka University, Dhaka, Bangladesh

I. Rashid Chowdhury
Department of Soil Science, Dhaka University, Dhaka, Bangladesh

Most tropical soils are well marked for their high capacity for phosphate fixation. When a soluble phosphatic fertilizer is applied to these soils, it undergoes various chemicals and physicochemical reactions and become intricately locked up in the soil and thus become unavailable to the plant. An attempt, therefore, has been made to study the phosphate fixation capacity of some acid soils of East Pakistan. Phosphorus availability of the soils increased significantly with the increased level of phosphorus application from 30 to 240 Ibs of phosphorus per acre, while 15 Ibs of phosphorus per acre could not substantially increase the availability except Brahmaputra soil where fixation seemed to be minimum. Highest phosphorus fixation had taken place in Cox's Bazar soil. This is true with all the methods. When Acetic Acid method was considered as an index of measurement, lowest fixation had taken place in Brahmaputra soil, Dhaka soils ranked between the two.

  Soil, Fertilize, Organic carbon, Phosphorus, Acid soil
  Cox's Bazar and Dhaka, Bangladesh
  00-00-1963
  
  Crop-Soil-Water Management
  Soil fertility

To determine the Phosphorus fixation capacity of some Acid soils of East Pakistan

Soil samples representing 0-6" depth and differing in texture and pH were collected from Cox's Bazar, Dhaka University Experiment station (Tejgaon), Govt. Agricultural Farm (Tejgaon), and Demra (Dhaka). The purpose of the experiment was to determine the phosphorus fixation capacity of these four soils. An experiment was set in the Soil Science green House of Dhaka University in 1963. Eight pounds of air dried soil, which was screened through two millimeter sieve was taken in each pot (excepting Cox's Bazar, where 3 Ibs of soil were used due to shortage of soil). The treatment one received no fertilizer with phosphoric acid (H3P04) at the rate of 15 Ibs., 30 lbs., 60 Ibs., 120 lbs., of elemental phosphorus per acre basis, respectively. The soil samples, obtained from each pot, were air-dried, ground and then screened through a two millimeter sieve. Three laboratory procedures were tested for the estimation of available phosphorus of all the soil samples. In all cases, the determinations were made by using Junior Coleman spectrophotometer after the development of blue color with ammonium molybdate and stannous chloride. The intensity measurement was made at 660 mu. The extractant used in Bray No.1 method was 0.03 N NH4F in HCI. The soil extractant ratio of I:0 was used and extraction time was five minutes. Troug's method (1930) as modified by Peech (1947) was used. 0.002 N H2S04 solution buffered to pH 3.0 with (NH4)2S04 was the extracting solution used. The soil solution ratio was 1:100 and the extraction period was 30 minutes. 0.5 N acetic acid which was originally proposed by Hibbard (1931) was the extractant used. The soil extractant ratio was 1:100 and the extraction period was two hours. Before fertilization and seeding, the soils were also mechanically and chemically analyzed. The methods adopted follow: (a) The soil was mechanically processed and screened through 2 millimeter sieve. The mechanical analysis was done by hydrometer method according to Piper (1951) and textural classes were determined from the triamgular coordinates as devised by U. S. Department of Agriculture (1951). (b) Organic carbon was determined volumetrically by wet-oxidation with K2Cr207 and H2S04 and rapid titration with normal FeS04 solution. (c) Available nitrogen (NH4-N and NO3-N) was determined on the N-KCI leachate of soil.Ammonical nitrogen was distilled over by magnesia and NO3-N by Devarda's alloy according to Piper (1951). (d) Available potassium was determined by precipitating potassium in Dyer's (1894) citric acid extract with sodium cobaltinitrite and oxidising the sodium-potassium cobaltinitrite with KMN04 following, Piper(l95I). (e) Exchangeable calcium was determined on the N-KClleachate of the soil by precipitating the Ca as calcium oxalate and finally titrating with KMN04 following, Piper (1951). (f) Exchangeable magnesium was determined on the KCI leachate. Mg precipitated, as magnesium pyrophosphate (Mg2P207) was determined gravimetrically following, Piper (1951). pH was determined colorimetrically using Lovibond comparator. The soil: water ratio was 1: 10.

  Pak. J. Soil Sci. 5 (1): 10-22, 1966
  
Funding Source:
1.   Budget:  
  

Highest phosphorus fixation had taken place in Cox's Bazar soil. This is true with all the methods. When Acetic Acid method was considered as an index of measurement, lowest fixation had taken place in Brahmaputra soil, Dhaka soils ranked between the two. This high rate of fixation by the three red soils may be due to reaction of phosphate with soluble iron, aluminium and manganese at very low pH, interaction with sesquioxide and hydrated oxides of these elements, adsorption on soil colloids and secondary adsorption by precipitated or adsorbed particles of phosphates. Fixation in Brahmaputra soil could be attributed to retention by calcium clay on the acid side of neutrality precipitation with divalent cations around pH 6, physico-chemical sorption ad secondary adsorption by precipitated or adsorbed particles of phosphates.

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