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Research Detail

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Jashim Uddin Ahmad
Department of Chemistry, Jahangirnagar University, Savar, Dhaka, Bangladesh

Mohammad Sayadur Rahman*
Chemistry Discipline, Khulna University, Khulna 9208, Bangladesh

The study presents the spatial and temporal patterns of river water chemistry at 25 sites in and around the Sundarbans. Conductivity, TDS, major cations, major anions, alkalinity, pH and hardness were determined during September 2008 to July 2009 in four seasons at Sarankhola, Chandpai, Nalian and Burigualiny from Bhola, Passur, Sipsa and Khulpatua rivers respectively. There is wide temporal variation in conductivity (from 201 µS/cm to 43.7 mS/cm) and TDS (0.13 to 31.2 g/L) from the eastern to western Sundarbans suggests low flow of fresh water into the western Sundarbans. Variation in major cations Na+ (9225 to 25 mg/L), K+ (4 to 510 mg/L), Ca+2 (26 to 273 mg/l) and Mg+2 (5 to 869) and major anions Cl- (13 to 13471 mg/L), HCO3 - (102 to 180 mg/L) and SO4 -2 (9 to 1414 mg/L) were also observed. Alkalinity, pH and hardness were 90 to 224 mg CaCO3/L, 6.5 to 8.3 and 85 to 4235 mg CaCO3/L respectively. Data on DO, BOD, COD, nutrients and heavy metals during 2001-2009 were collected from secondary sources. Dissolved oxygen (4.9 to 6.9 mg/L) is within the Environmental Quality Standard (EQS) of Bangladesh. BOD and COD are higher in coast than the inner part of the Sundarbans. Ammonium (0.04 to 6.74 mg/L), nitrate (0.1 to 1.4mg/L) and phosphate (0.026 to 0.252 mg/L) are present in sufficient quantity for aquatic life to survive. Heavy metal concentrations are exceeded in some areas. The study reveals that water chemistry of the Sundarbans Mangrove Forest are approaching critical value for the survival of organism. 

  Sundarbans mangrove forests, Water chemistry, Salinity, Nutrients
  Around the Sundarbans Mangrove Forest, Southwest Bangladesh
  
  
  Crop-Soil-Water Management
  Water quality

It is important to determine the processes that regulate stream water chemistry in landscapes under increasing pressure from human population, whether from urbanization or more intensive food production. In Bangladesh there is no regular monitoring work regarding the collection of water quality datasets particularly Sundrabans aquatic ecosystem. There is paucity of information on the variability in river water chemistry in relation to catchment characteristics for the Sundarbans river system. This paper presents the water chemistry of the Sundarbans with relation to its catchment characteristics.

Bangladesh Sundarbans, is divided into four ranges namely Sarankhola, Chandpai, Nalianala and Burigoalini for its management. Water samples were collected near Sarankhola, Chandpai, Nalian and Burigualiny stations situated in upstream of four major river-sytems Bhola-Bolesware, Passur, Sibsa, and Khulpatua-Arpangasia during 2008-2009 in four seasons (dry: December to February; pre-monsoon: March to May; monsoon: June to August; and post-monsoon: September to November). In situ measurements for EC/TDS and pH were carried out by applying a portable EC meter with temperature sensor (Lutron CD 4301), a portable pH meter with accuracy ± 0.1 pH units (Hanna HI 98106). Quadruplicate surface water samples were collected from each of the rivers in upstream covering main rivers and creeks. Water samples for dissolved metal concentrations, calcium (Ca2+), magnesium (Mg2+), sodium (Na+), and potassium (K+) were acidified to pH<2 with HNO3 (65% conc.). Sodium and potassium were determined by flame photometer (Jenoy, England). Alkalinity, hardness, calcium, magnesium, chloride, bicarbonate and sulphate were determined in laboratory following standard methods (APHA, 1992). All sites were sampled during day time covering high and low tide.

Water chemistry data from 25 locations between 2001 and 2009 were collected from different sources such as FMRTD (2001), JOECLA (2002), IWM (2003), Rahaman et. al. (2003), Rahaman (2006) and Ara et. al.,(2009). The parameters are conductivity, TDS, pH, alkalinity, hardness, dissolved oxygen (DO), biochemical oxygen demand (BOD), chemical oxygen demand (COD), major cations (Na,+ K,+ Ca2+, and Mg2+), major anions (Cl-, SO4 2-, HCO3-), nutrients (NH4 + , NO3 - and PO4 3-), and heavy metals (Cr, Mn, Fe, Co, Ni, Cu, Zn, Pb). Tidal context was excluded in this analysis.

 

  Khulna University Studies Special Issue (SESB 2010): 9-20 : June, 2010
  
Funding Source:
1.   Budget:  
  

It is observed that human activities in the region have no significant imprint on river water chemistry. Detail chemical data especially on redox chemistry of the Sundarbans are lacking. There are very few studies on river water chemistry of SMF. It is important to monitor regularly considering the rapid industrial and agricultural development around the forests. The importance of nutrient inputs from non-point sources in coastal belt of the western Sundarbans is critical in relation to effective catchment management. River water chemistry (especially N and P concentrations) is highly variable due to a complex set of interacting hydrological and biogeochemical processes. Many parameters of water chemistry of the Sundarbans are approaching the critical value for the survival of different aquatic organisms. The addition of flow data and soil physico-chemical data would strengthen the value in terms of linking water quality and change to catchment hydrology and biogeochemistry. Integration of GIS approaches and extensive monitoring data can provide a base for underpinning environmental management at local, regional, national and international scales. 

  Journal
  


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